The Oxidation of Cyclic Ketones by H2O2 Catalyzed by Cu(II) and Fe(III) Coordination Polymers

Authors

  • Emir N. Abdullayev L.V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Ukraine
  • Andrii M. Mishura L.V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Ukraine
  • Ievgenii A. Iermolenko Enamine Ltd.; Institute of Organic Chemistry of the National Academy of Sciences of Ukraine, Ukraine
  • Anton S. Lytvynenko L. V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Ukraine https://orcid.org/0000-0001-5528-9989
  • Maksim O. Kolosov V. N. Karazin Kharkiv National University, Ukraine https://orcid.org/0000-0002-6714-0513
  • Olena G. Shvets V. N. Karazin Kharkiv National University, Ukraine https://orcid.org/0000-0003-4791-2114
  • Kostyantyn S. Gavrilenko Enamine Ltd.; Taras Shevchenko National University of Kyiv, Ukraine https://orcid.org/0000-0001-7487-6660
  • Sergiy V. Kolotilov L. V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of Ukraine, Ukraine https://orcid.org/0000-0002-4780-4378

DOI:

https://doi.org/10.24959/ophcj.24.315358

Keywords:

catalytic oxidation, cyclic ketones, hydrogen peroxide, porous coordination polymers, copper(II), iron(III)

Abstract

It has been shown that the oxidation of ketones – analogs of cyclohexanone – by hydrogen peroxide in the presence of Cu3(btc)2 (btc3- = 1,3,5-benzenetricarboxylate) occurred mainly by the radical mechanism, rather than by the Baeyer-Villiger reaction mechanism, and led to a mixture of products formed due to the ring cleavage and reduction of the hydrocarbon chain length. Unlike aliphatic ketones, α-tetralone hardly underwent conversion in the reaction with H2O2 in the presence of HKUST-1, and the oxidation of the same ketone in the presence of Fe2(OH)3(btc) led to the formation of a number of products; among them, 1,4-naphthoquinone was dominant.

Supporting Agency

  • The authors received no specific funding for this work.

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Published

2025-02-19

How to Cite

(1)
Abdullayev, E. N.; Mishura, A. M.; Iermolenko, I. A.; Lytvynenko, A. S.; Kolosov, M. O.; Shvets, O. G.; Gavrilenko, K. S.; Kolotilov, S. V. The Oxidation of Cyclic Ketones by H2O2 Catalyzed by Cu(II) and Fe(III) Coordination Polymers. J. Org. Pharm. Chem. 2025, 22, 25-35.

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Vol. 22 No. 4 (2024): Issue in Progress

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Original Researches

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