Oleksandr Ishchenko: And Gladly Would He Learn, and Gladly Teach

Authors

DOI:

https://doi.org/10.24959/ophcj.25.343780

Keywords:

polymethine dyes, color theory, electronic structure, material science, history of chemistry

Abstract

The Ukrainian school of organic dye chemistry has long received worldwide recognition. Among the scientists whose achievements embody this success is Academician Oleksandr Oleksandrovych Ishchenko. Over more than half a century of fruitful research at the Department of Color and Structure of Organic Compounds of the Institute of Organic Chemistry of the National Academy of Sciences of Ukraine, he laid the foundations for the rational design of functional dyes for light-energy conversion, particularly for various laser technologies; became one of the pioneers of polymethine ion-pair photonics; developed methodological approaches to the study of electronic absorption and fluorescence spectra using the method of moments, which provided new insights into the electronic structure of organic chromophores; and made a significant contribution to the systematic study and interpretation of the solvatochromism of polymethines of different types. The driving force behind all these achievements was his enduring passion for science — a deep desire to learn and share knowledge with future generations of researchers.

 

Supporting Agency

  • The author received no specific funding for this work.

Downloads

Download data is not yet available.

References

  1. Ishchenko, A. A.; Derevyanko, N. A.; Kudinova, M. A.; Dyadyusha, G. G.; Tolmachev, A. I. Chemical Structure and Shape of the Absorption Bands of Pyrylocyanine Dyes. Theoretical and Experimental Chemistry 1978, 13 (6), 628–630. https://doi.org/10.1007/BF00520821.
  2. Dyadyusha, G. G.; Ishchenko, A. A. Application of the Method of Moments to the Study of the Electronic Spectra of Organic Dyes. Journal of Applied Spectroscopy 1979, 30 (6), 746–750. https://doi.org/10.1007/BF00615763.
  3. Catalán, J. On the Mirror Symmetry between the Absorption and Emission of Complex Molecules in Solution. Journal of Physical Organic Chemistry 2020, 33 (3), e4034. https://doi.org/10.1002/poc.4034.
    |
  4. Dyadyusha, G. G.; Ishchenko, A. A.; Derevyanko, N. A.; Tolmachev, A. I. Absorption Bandwidth of Isomeric Polymethine Dyes. Journal of Applied Spectroscopy 1984, 41 (6), 1400–1404. https://doi.org/10.1007/BF00659321.
  5. Ishchenko, A. A. Laser Media Based on Polymethine Dyes. Quantum Electronics 1994, 24 (6), 471–492. https://doi.org/10.1070/qe1994v024n06abeh000122.
  6. Ishchenko, A. A. Physicochemical Aspects of the Creation of Modern Light-Sensitive Materials Based on Polymethine Dyes. Theoretical and Experimental Chemistry 1998, 34 (4), 191–210. https://doi.org/10.1007/BF02523249.
  7. Ishchenko, A. A.; Derevyanko, N. A.; Svidro, V. A. Constitution and Fluorescence Spectra of Unsymmetrical Polymethine Dyes. Dyes and Pigments 1992, 19 (3), 169–177. https://doi.org/10.1016/0143-7208(92)80023-G.
    |
  8. Ishchenko, A. A.; Svidro, V. A.; Derevyanko, N. A. Solvatofluorochromy of Cationic Cyanine Dyes. Dyes and Pigments 1989, 10 (2), 85–96. https://doi.org/10.1016/0143-7208(89)85001-6.
    |
  9. Dyadyusha, G. G.; Ishchenko, A. A.; Derevyanko, N. A.; Tolmachev, A. I. Study of Ionic Equilibria of Indotricarbocyanines in Aromatic Hydrocarbons. Doklady Physical Chemistry 1982, 264 (2), 351–355.
  10. Komarov, I. V.; Turov, A. V.; Kornilov, M. Yu.; Derevyanko, N. A.; Ishchenko, A. A. Study of the Chemical Structure of Ion Pairs of Cationic Cyanine Dyes in Weakly Polar Solvents by the Method of PMR Spectroscopy with the Use of Lanthanide Shift Reagents. Journal of General Chemistry of the USSR 1989, 59 (10), 2110–2115.
  11. Komarov, I. V.; Turov, A. V.; Ishchenko, A. A.; Derevyanko, N. A.; Kornilov, M. Yu. Study of the Structure of Ion Pairs of Cationic Cyanine Dyes Using Lanthanide Chelates and NMR Quadrupole Nuclei. Doklady. Chemistry 1989, 306 (5), 178–181.
  12. Ishchenko, A. A. Photonics and Molecular Design of Dye-Doped Polymers for Modern Light-Sensitive Materials. Pure and Applied Chemistry 2008, 80 (7), 1525–1538. https://doi.org/10.1351/pac200880071525.
    |
  13. Ishchenko, A. A. Structure and Spectral-Luminescent Properties of Polymethine Dyes [in Russian]; Naukova Dumka: Kyiv, 1994.
  14. Davidenko, N. A.; Ishchenko, A. A.; Kuvshinsky, N. G. Photonics of Molecular Semiconductor Composites Based on Organic Dyes [in Russian]; Naukova Dumka: Kyiv, 2005.
  15. Bulavko, G. V.; Ishchenko, A. A. Organic Photovoltaic Structures [in Ukrainian]; Naukova Dumka: Kyiv, 2023. https://doi.org/10.15407/978-966-00-1839-6.
  16. Bezrodnyĭ, V. I.; Ishchenko, A. A.; Karabanova, L. V; Slominskiĭ, Y. L. Highly Stable Polymethine-Dye-Based Polymer Switches for Passive Mode Locking in Neodymium Lasers. Quantum Electronics 1995, 25 (8), 819–822. https://doi.org/10.1070/QE1995v025n08ABEH000477.
    |
  17. Bezrodnyi, V. I.; Ishchenko, A. A. High Efficiency Lasing of a Dye-Doped Polymer Laser with 1.06 Μm Pumping. Applied Physics B: Lasers and Optics 2001, 73 (3), 283–285. https://doi.org/10.1007/s003400100646.
    |
  18. Bezrodna, T.; Bezrodnyi, V.; Ishchenko, A.; Slominskii, Y.; Sharanov, I. New Polymethine Dyes for Liquid and Polymer Passive Q-Switches of Neodymium Lasers. Optik 2022, 267, 169725. https://doi.org/10.1016/j.ijleo.2022.169725.
    |
  19. Bezrodnyĭ, V. I.; Derevyanko, N. A.; Ishchenko, A. A.; Slominskiĭ, Y. L. Polymer Passive Laser Switches for Stimulated Emission in the Region of 1.3 Μm. Quantum Electronics 1995, 25 (8), 823–825. https://doi.org/10.1070/QE1995v025n08ABEH000478.
    |
  20. Kulinich, A. V.; Ishchenko, A. A. Electronic Structure and Spectral-Fluorescent Properties of Merocyanine [in Ukrainian]; Naukova Dumka: Kyiv, 2022.
  21. Kulinich, A. V.; Ishchenko, A. A. Merocyanines: Electronic Structure and Spectroscopy in Solutions, Solid State, and Gas Phase. Chemical Reviews 2024, 124 (21), 12086–12144. https://doi.org/10.1021/acs.chemrev.4c00317.
    | |
  22. Kulinich, A. V.; Ishchenko, A. A.; Bondarev, S. L.; Knyukshto, V. N. Low-Temperature Effect on the Electronic Structure and Spectral-Fluorescent Properties of Highly Dipolar Merocyanines. Journal of Physical Chemistry A 2018, 122 (50), 9645–9652. https://doi.org/10.1021/acs.jpca.8b09522.
    | |
  23. Kulinich, A. V.; Ishchenko, A. A.; Bondarev, S. L.; Knyukshto, V. N. Effect of Donor and Acceptor End-Groups on Electronic Structure and Spectral-Fluorescent Properties of Merocyanines in Frozen Ethanol. Journal of Photochemistry and Photobiology A: Chemistry 2021, 405, 112932. https://doi.org/10.1016/j.jphotochem.2020.112932.
    |
  24. Ishchenko, A. A.; Kulinich, A. V.; Bondarev, S. L.; Raichenok, T. F. UV–Vis Absorption Spectra and Electronic Structure of Merocyanines in the Gas Phase. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 2018, 190, 332–335. https://doi.org/10.1016/j.saa.2017.09.054.
    | |
  25. Kulinich, A. V.; Ishchenko, A. A.; Chibisov, A. K.; Zakharova, G. V. Effect of Electronic Asymmetry and the Polymethine Chain Length on Photoprocesses in Merocyanine Dyes. Journal of Photochemistry and Photobiology A: Chemistry 2014, 274, 91–97. https://doi.org/10.1016/j.jphotochem.2013.09.016.
    |
  26. Voiciuk, V.; Redeckas, K.; Derevyanko, N. A.; Kulinich, A. V.; Barkauskas, M.; Vengris, M.; Sirutkaitis, V.; Ishchenko, A. A. Study of Photophysical Properties of a Series of Polymethine Dyes by Femtosecond Laser Photolysis. Dyes and Pigments 2014, 109, 120–126. https://doi.org/10.1016/j.dyepig.2014.05.012.
    |

Downloads

Published

2025-09-24

How to Cite

(1)
Kulinich, A. V. Oleksandr Ishchenko: And Gladly Would He Learn, and Gladly Teach. J. Org. Pharm. Chem. 2025, 23, 36-42.

Issue

Section

Life Devoted to Science